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    • 专利摘要:
    A method of manufacturing a part (20) comprising the formation of successive metal layers (201… 20n), superimposed on each other, each layer being formed by the deposition of a filler metal (15, 25), the filler metal being subjected to an energy input so as to melt and to form, by solidifying, said layer, the process being characterized in that the filler metal (15,25) is an alloy of aluminum comprising the following alloying elements (% by weight): Fe: 2% to 8%, and preferably 2% to 6%, more preferably 3 to 5%; optionally Zr: 0.5% to 2.5% or 0.5 to 2% or 0.7 to 1.5%; optionally Si: <1%, or even <0.5% or even <0.2%, or even <0.05%; optionally Cu: ≤ 0.5%, or even <0.2%, or even <0.05%; optionally Mg: ≤ 0.2%, preferably ≤ 0.1%, preferably <0.05%; optionally other alloying elements <0.1% individually and in total <0.5%; impurities: <0.05%, or even <0.01% individually, and in total <0.15%; remains aluminum. FIGURES
    公开号:FR3086954A1
    申请号:FR1908678
    申请日:2019-07-30
    公开日:2020-04-10
    发明作者:Bechir Chehab
    申请人:C Tec Constellium Technology Center SAS；
    IPC主号:
    专利说明:

    Description
    Title of the invention: Process for manufacturing an aluminum alloy part
    Technical field The technical field of the invention is a method of manufacturing an aluminum alloy part, using an additive manufacturing technique.
    Prior art [0002] Since the 1980s, additive manufacturing techniques have developed. They consist in shaping a part by adding material, which is the opposite of machining techniques, which aim to remove material. Formerly confined to prototyping, additive manufacturing is now operational for mass production of industrial products, including metal parts.
    The term "additive manufacturing" is defined according to French standard XP E67-001 as a set of methods for manufacturing, layer by layer, by adding material, a physical object from a digital object. ASTM F2792 (January 2012) also defines additive manufacturing. Different additive manufacturing methods are also defined and described in ISO / ASTM 17296-1. The use of additive manufacturing to produce an aluminum part, with low porosity, has been described in document WO2015006447. The application of successive layers is generally carried out by application of a so-called filler material, then fusion or sintering of the filler material using an energy source of the laser beam, electronic beam, plasma torch type. or electric arc. Whatever the additive manufacturing method applied, the thickness of each added layer is of the order of a few tens or hundreds of microns.
    Other additive manufacturing methods can be used. Let us cite for example, and without limitation, the melting or sintering of a filler material taking the form of a powder. It can be fusion or laser sintering. Patent application US20170016096 describes a method of manufacturing a part by localized fusion obtained by the exposure of a powder to an energy beam of electron beam or laser beam type, the method also being designated by acronyms Anglosaxons SLM, meaning Selective Laser Melting or EBM, meaning Electro Beam Melting.
    The mechanical properties of the aluminum parts obtained by additive manufacturing depend on the alloy forming the filler metal, and more precisely on its composition as well as on the heat treatments applied following the implementation of additive manufacturing.
    The Applicant has determined an alloy composition which, used in an additive manufacturing process, makes it possible to obtain parts with remarkable mechanical performance, without it being necessary to implement heat treatments of the implementation type. solution and quenching. In addition, the parts used have interesting properties of thermal conductivity or electrical conductivity. This allows to diversify the possibilities of applications of these parts.
    STATEMENT OF THE INVENTION A first object of the invention is a method of manufacturing a part comprising the formation of successive metal layers, superimposed on each other, each layer being formed by the deposition of a metal d filler, the filler metal being subjected to a supply of energy so as to enter into fusion and to constitute, by solidifying, said layer, the process being characterized in that the filler metal is an alloy of aluminum comprising the following alloying elements (% by weight):
    - Fe: 2% to 8%, and preferably 2% to 6%, more preferably 3 to 5%;
    - possibly Zr: 0.5% to 2.5% or 0.5 to 2% or 0.7 to 1.5%;
    - possibly Si: <1%, even <0.5% or even <0.2%, even <0.05%;
    - possibly Cu: <0.5%, even <0.2%, even <0.05%;
    - optionally Mg: <0.2%, preferably <0.1% preferably <0.05%;
    - possibly other alloying elements <0.1% individually and in total <0.5%;
    - impurities: <0.05%, even <0.01% individually, and in total <0.15%; Aluminum remains.
    Preferably, the amount of Fe is greater than the amount of Zr.
    Other alloying elements include, for example, Cr, V, Ti, Mn, Mo, W, Nb, Ta, Sc, Ni, Zn, Hf, Nd, Ce, Co, La, Ag, Li, Y, Yb, Er, Sn, In, Sb, Sr, Ba, Bi, Ca, P, B and / or mischmetal.
    The process can include the following characteristics, taken in isolation or in technically feasible combinations:
    - The alloy does not contain Cr, V, Mn, Ti, Mo, or in a mass fraction of less than 500 ppm, 300 ppm, 200 ppm, or even less than 100 ppm;
    the mass fraction of each other alloying element is less than 500 ppm, or even 300 ppm, even less than 200 ppm, even less than 100 ppm;
    - the mass fraction of Zr is strictly less than 0.5%, or even 0.2% or even 0.05%;
    - the mass fraction of Si is strictly less than 0.5%, or even 0.2% or even 0.05%;
    [0015] [0016] [0017] [0018] [0019] [0020] [0021] [0022] [0023]
    Fe: 2% to 8% and Zr: 0.5% to 2.5% and Si: <0.5%;
    Fe: 2% to 8% and Zr <0.5% and Si: <0.5%;
    Fe:> 3% and <8%.
    Each layer can in particular describe a pattern defined from a digital model.
    The process may include, following the formation of the layers, an application of at least one heat treatment. The heat treatment can be or include tempering or annealing, which can for example be carried out at a temperature preferably between 200 ° C. and 500 ° C.
    The heat treatment can then be carried out:
    - At a temperature between 200 ° C and less than 400 ° C, preferably from 320 to 380 ° C, in which case the duration of the heat treatment is between 0.1 and 20 hours;
    - Or at a temperature between 400 ° C and 500 ° C, in which case the duration of the heat treatment is preferably between 0.1 and 5 hours.
    The heat treatment can also include dissolving and quenching, even if it is preferred to avoid them. It can also include hot isostatic compression.
    According to an advantageous embodiment, the method does not include quenching following the formation of the layers or the heat treatment. Thus, preferably, the process does not include steps of dissolving followed by quenching.
    According to another embodiment, the filler metal comes from a filler wire, the exposure of which to a heat source, for example an electric arc, results in a localized melting followed by solidification, so as to form a solid layer. According to one embodiment, the filler metal takes the form of a powder, the exposure of which to a beam of light or of charged particles results in a localized melting followed by solidification, so as to form a solid layer. .
    A second object of the invention is a metal part, obtained after application of a method according to the first object of the invention.
    A third object of the invention is a filler material, in particular a filler wire or a powder, intended to be used as a filler material for an additive manufacturing process, characterized in that it is made of an aluminum alloy, comprising the following alloying elements (by weight):
    - Fe: 2% to 8%, and preferably 2% to 6%, more preferably 3 to 5%;
    - optionally Zr: 0.5% to 2.5% or 0.5 to 2% or 0.7 to 1.5%;
    - possibly Si: <1%, even <0.5% or even <0.2%, even <0.05%;
    - possibly Cu: <0.5%, even <0.2%, even <0.05%;
    - optionally Mg: <0.2%, preferably <0.1% preferably <0.05%;
    - possibly other alloying elements <0.1% individually and in total <0.5%;
    - impurities: <0.05%, even <0.01% individually, and in total <0.15%;
    Aluminum remains.
    The aluminum alloy forming the filler material may have the characteristics described in connection with the first object of the invention.
    The filler material may be in the form of a powder. The powder can be such that at least 80% of the particles making up the powder have an average size in the following range: 5 μm to 100 μm, preferably from 5 to 25 μm, or from 20 to 60 μm.
    When the filler material is in the form of a wire, the diameter of the wire can in particular be comprised from 0.5 mm to 3 mm, and preferably comprised from 0.5 mm to 2 mm, and more preferably from 1 mm to 2 mm.
    Other advantages and characteristics will emerge more clearly from the description which follows of particular embodiments of the invention, given by way of nonlimiting examples, and represented in the figures listed below.
    Brief description of the drawings [fig.l] Figure 1 is a diagram illustrating an additive manufacturing process of the SLM type.
    [Fig.2] Figure 2 illustrates the properties of traction and electrical conduction determined during experimental tests, from samples manufactured using an additive manufacturing process according to the invention.
    [Fig.3] Figure 3 is a diagram illustrating an additive manufacturing process of the type
    WAAM.
    [Fig.4] Figure 4 is a diagram of the test tube used according to the examples.
    [Fig.5] Figure 5 is a diagram of the second test pieces of the example.
    EXPLANATION OF PARTICULAR EMBODIMENTS In the description, unless otherwise indicated:
    - the designation of aluminum alloys conforms to the nomenclature of The Aluminum Association;
    - the contents of chemical elements are designated in% and represent mass fractions. The notation x% - y% means greater than or equal to x% and less than or equal to y%.
    By impurity is meant chemical elements present in the alloy unintentionally.
    Figure 1 shows schematically the operation of an additive manufacturing process of the selective laser melting type (Selective Laser Melting or SLM). The filler metal 15 is in the form of a powder placed on a support 10. A source of energy, in this case a laser source 11, emits a laser beam 12. The laser source is coupled to the filler material by an optical system 13, whose movement is determined according to a digital model M. The laser beam 12 propagates along a propagation axis Z, and follows a movement along an XY plane, describing a pattern depending on the digital model. The plane is for example perpendicular to the axis of propagation Z. The interaction of the laser beam 12 with the powder 15 generates a selective fusion of the latter, followed by solidification, resulting in the formation of a layer 20i. .20 n . When a layer has been formed, it is covered with powder 15 of the filler metal and another layer is formed, superimposed on the layer previously produced. The thickness of the powder forming a layer may for example be between 10 and 200 μm.
    The powder can have at least one of the following characteristics:
    - Average particle size from 5 to 100 µm, preferably from 5 to 25 µm, or from 20 to 60 µm. The values given mean that at least 80% of the particles have an average size in the specified range.
    - Spherical shape. The sphericity of a powder can for example be determined using a morphogranulometer.
    - Good flowability. The flowability of a powder can for example be determined according to standard ASTM B213 or standard ISO 4490: 2018. According to ISO 4490: 2018, the flow time is preferably less than 50 s.
    - Low porosity, preferably from 0 to 5%, more preferably from 0 to 2%, even more preferably from 0 to 1% by volume. The porosity can in particular be determined by image analysis from optical micrographs or by helium pycnometry (see standard ASTM B923).
    - Absence or small quantity (less than 10%, preferably less than 5% by volume) of small particles (1 to 20% of the average size of the powder), called satellites, which stick to the larger particles.
    The implementation of such a process allows parts to be manufactured at a high yield, up to 40 cm 3 / h.
    The Applicant has observed that the application of heat treatments of the quenching type could induce distortion of the part, due to the sudden variation in temperature. The distortion of the part is generally all the more significant as its dimensions are important. However, the advantage of an additive manufacturing process is precisely to obtain a part whose shape, after manufacture is final, or almost final. The occurrence of significant deformation resulting from heat treatment is therefore to be avoided. By quasi-final, it is understood that a finishing machining can be carried out on the part after its manufacture: the part manufactured by additive fa6 brication extends according to its final shape, except for the finishing machining.
    Having noted the above, the Applicant has sought an alloy composition, forming the filler material, making it possible to obtain acceptable mechanical properties, without requiring the application of heat treatments, subsequent to the formation of the layers. , which may cause distortion. This is particularly to avoid heat treatments involving a sudden change in temperature. Thus, the invention makes it possible to obtain, by additive manufacturing, a part whose mechanical properties are satisfactory, in particular in terms of elastic limit. Depending on the type of additive manufacturing process chosen, the filler material may be in the form of a wire or a powder.
    The Applicant has found that by limiting the number of elements present in the alloy, beyond a content of 1%, a good compromise is obtained between the interesting mechanical and thermal properties. It is usually accepted that the addition of elements in the alloy makes it possible to improve certain mechanical properties of the part produced by additive manufacturing. By mechanical properties is meant, for example, the elastic limit or the elongation at break. However, the addition of too much, or too much diversity, of alloying chemical elements can adversely affect the heat conduction properties of the part resulting from additive manufacturing. Thus, the use of binary or ternary alloys in an additive manufacturing process constitutes a promising avenue in the field of additive manufacturing.
    The Applicant considered that it was useful to reach a compromise between the number and the quantity of elements added to the alloy, so as to obtain acceptable mechanical and thermal (or electrical) properties.
    The Applicant considers that such a compromise is obtained by limiting to one or two the number of chemical elements forming the aluminum alloy having a mass fraction greater than or equal to 1% or 0.5% . Thus, a particularly advantageous alloy can be obtained by adding, according to a mass fraction greater than 1% or 0.5%:
    - only Le, with Le: 2% to 8%, in which case the alloy consists essentially of two elements (Al and Le);
    - or Le (with Le: 2% to 8%) and Zr (with Zr: 0.5% to 2.5%), in which case the alloy consists essentially of three elements (Al, Le and Zr). The presence of Zr generally improves the mechanical properties after heat treatment.
    The alloy can also include other alloying elements, such as Cr, V, Ti, Mn, Mo, W, Nb, Ta, Sc, Ni, Zn, Hf, Nd, Ce, Co, La , Ag, Li, Y, Yb, Er, Sn, In, Sb, Sr, Ba, Bi, Ca, P, B and / or mischmetal individually having a content <0.1% by weight. However, some of these alloying elements, in particular Cr, V, Ti and Mo degrade the conductivity so it is preferable to avoid them. Cu is considered to be less harmful with respect to thermal conductivity.
    The addition of Mg in the absence of a solution-quenching-tempering treatment, would lower the electrical or thermal conductivity without significant impact on the mechanical properties. To this is added its tendency to evaporate during the atomization and SLM process, especially for alloys with high liquidas like those tested according to the present invention. Thus, according to a variant, the alloy used according to the present invention does not comprise Mg or else according to an amount of impurity, ie <0.05%.
    When the other alloying elements are, for example Y, Yb, Er, Sn, In, Sb, these elements are preferably present individually according to a mass fraction strictly less than 500 ppm, and preferably strictly less than 300 ppm , or even 200 ppm, even 100 ppm.
    It should be noted that, preferably, the alloys according to the present invention are not alloys of the AA6xxx type, due to the absence of simultaneous addition of Si and Mg in amounts greater than 0.2%.
    Experimental examples A test was carried out using a binary alloy, the composition of which included Fe 4%; impurities and other alloying elements: <0.05% individually.
    Test pieces were produced by SLM, using a machine of the EOS290 SLM type (supplier EOS). The laser power was 370 W. The scanning speed was 1400 mm / s. The difference between two adjacent scanning lines, usually designated by the term vector deviation, was 0.11 mm. The layer thickness was 60 µm, with heating of the build plate to 200 ° C.
    The powder used had a particle size essentially between 3 µm and 100 µm, with a median of 40 µm, a 10% fractile of 16 µm and a 90% fractile of 79 µm.
    First test pieces were produced in the form of vertical cylinders relative to the construction plate (direction Z) with a diameter of 11 mm and a height of 46 mm. Second test pieces were produced, taking the form of parallelepipeds of dimensions 12 (direction X) x 45 (direction Y) x 46 (direction Z) mm (see Figure 5). All parts have undergone a 4-hour SLM post-relaxation treatment at 300 ° C.
    Some first parts have undergone post-production heat treatment at 350 ° C, 400 ° C or 450 ° C, the duration of the treatment being from 1 h to 104 h. All of the first parts (with and without post-production heat treatment) were machined to obtain cylindrical tensile test pieces having the following characteristics in mm (see Table 1 and Figure 4):
    In Figure 4 and Table 1, 0 represents the diameter of the central part of the test piece, M the width of the two ends of the test piece, LT the total length of the test piece, R the radius of curvature between the central part and the ends of the test piece, The length of the central part of the test piece and F the length of the two ends of the test piece.
    [Tables 1]
    Type 0 M LT R The F TOR 4 4 8 45 3 22 8.7
    These cylindrical specimens were tested in tension at room temperature according to standard NF EN ISO 6892-1 (2009-10).
    Some second test pieces have undergone post-production heat treatment, as described in connection with the first pieces. The second test pieces were subjected to electrical conductivity tests, based on the fact that the electrical conductivity changes in a similar way to the thermal conductivity. A linear dependence relation of thermal conductivity and electrical conductivity, according to the law of Wiedemann Franz, was validated in the publication Hatch Aluminum properties and physical metallurgy ASM Metals Park, OH, 1988. The second test pieces underwent a surface polishing on each side of 45 mm x 46 mm for conductivity measurements using abrasive paper with roughness 180. The electrical conductivity measurements were carried out on the polished faces using a measuring device type Eoerster Sigmatest 2.069 at 60 kHz.
    Table 2 below represents, for each first test piece, the heat treatment temperature (° C), the heat treatment time, the elastic limit at 0.2% Rp0.2 (MPa) , tensile strength (Rm), elongation at break A (%), as well as electrical conductivity (MS.ni 1 ). The tensile properties (yield strength, tensile strength and elongation at break) were determined from the first test pieces, according to manufacturing direction Z, while the electrical properties (thermal conductivity) were determined on the second test pieces. In Table 2 below, the duration of Oh corresponds to an absence of heat treatment.
    [Tables!]
    Duration(h) Temperaturee(° C) Rp0.2 (MPa) Rm(MPa) AT (%) σ (MS / m) 0 - 282 405 4.5 24.64 1 400 262 378 7.4 24.84 4 400 217 313 11.3 26.5 10 400 187 362 14.7 27.57 100 400 152 303 22 28.93 104 450 136 272 18.6 29.82 14 350 268 228 6.2 25.51 56 350 215 199 9.9 25.61
    [0064] [0065] [0066] [0067] [0068]
    In the absence of heat treatment, the elastic limit Rp0.2 reaches 282 MPa, and the elongation at break is equal to 4.5%. The application of a heat treatment makes it possible to reduce the elastic limit, but it makes it possible to increase the electrical conductivity as well as the elongation at break. It can be seen that the elongation at break is always greater than 3%.
    In the absence of heat treatment, the mechanical properties of the manufactured part are considered to be satisfactory. When seeking to favor a compromise between mechanical properties and thermal or electrical conduction properties, it is preferable to apply a heat treatment, and for example:
    - from 200 ° C to less than 400 ° C, the duration being from 0.1 to 20 hours;
    - from 400 ° C to 500 ° C, the duration being from 0.1 to 5 hours.
    When a heat treatment is applied in order to improve the thermal or electrical conduction properties, it is preferable that its temperature is less than 500 ° C or preferably less than 450 ° C, and for example between 100 ° C and 450 ° C. It can in particular be an income or an annealing. Its duration can exceed 10 hours, even 100 hours.
    Ligure 2 illustrates the tensile properties (ordinate axis, representing the elastic limit Rp0.2) as a function of thermal conductivity properties (abscissa axis, representing thermal conductivity). It is recalled that the thermal conduction properties are assumed to be representative of the electrical conduction properties. In Ligure 2, the percentages indicate the elongation at break. The term No TTH means no heat treatment.
    Such a binary alloy has a relatively low liquidus temperature (of the order of 660 ° C), which allows good ability to be atomized using standard industrial atomizers for aluminum alloys. The liquidas was determined from the powder.
    The relative density of the samples is greater than 99%, which translates a porosity <1% measured by image analysis on a polished section of samples.
    According to one embodiment, the method may include hot isostatic compression (CIC). CIC treatment can notably improve the elongation properties and fatigue properties. Hot isostatic compression can be performed before, after or in place of the heat treatment. Advantageously, the hot isostatic compression is carried out at a temperature of 250 ° C to 500 ° C and preferably from 300 ° C to 450 ° C, at a pressure of 500 to 3000 bars and for a period of 0.5 to 50 hours.
    The possible heat treatment and / or hot isostatic compression makes it possible in particular to increase the electrical or thermal conductivity of the product obtained.
    According to another embodiment, suitable for structural hardening alloys, it is possible to carry out a solution followed by quenching and tempering of the formed part and / or hot isostatic compression. The hot isostatic compression can in this case advantageously replace the dissolution.
    However, the method according to the invention is advantageous, since it preferably does not require a solution treatment followed by quenching. Dissolution can have a detrimental effect on the mechanical resistance in certain cases by participating in a magnification of the dispersoids or of the fine intermetallic phases.
    According to one embodiment, the method according to the present invention also optionally comprises a machining treatment, and / or a chemical, electrochemical or mechanical surface treatment, and / or a tribofinishing. These treatments can be carried out in particular to reduce the roughness and / or improve the corrosion resistance and / or improve the resistance to initiation of fatigue cracks.
    Optionally, it is possible to carry out mechanical deformation of the part, for example after additive manufacturing and / or before the heat treatment.
    Although described in connection with an additive manufacturing method of the SLM type, the method can be applied to other additive manufacturing methods of the WAAM type, mentioned in connection with the prior art. Ligure 3 represents such an alternative. An energy source 31, in this case a torch, forms an electric arc 32. In this device, the torch 31 is held by a welding robot 33. The part 20 to be manufactured is placed on a support 10. In this example, the manufactured part is a wall extending along a transverse axis Z perpendicular to a plane XY defined by the support 10. Under the effect of the electric arc 12, a filler wire 35 melts to form a weld bead. The welding robot is controlled by a digital model M. It is moved so as to form different layers 20 i ... 20 n , stacked on each other, forming the wall 20, each layer corresponding to a weld bead. Each layer 20i ... 20 n extends in the XY plane, according to a pattern defined by the digital model M.
    The diameter of the filler wire is preferably less than 3 mm. It can be understood from 0.5 mm to 3 mm and is preferably understood from 0.5 mm to 2 mm, or even from 1 mm to 2 mm. It is for example 1.2 mm.
    Other methods can also be envisaged, for example, and without limitation:
    - selective laser sintering (Selective Laser Sintering or SLS);
    Direct metal sintering by laser (Direct Metal Laser Sintering or DMLS);
    - selective sintering by heating (Selective Heat Sintering or SHS);
    - electron beam fusion (Electron Beam Melting or EBM);
    - laser melting deposition;
    - direct deposit by energy supply (Direct Energy Deposition or DED);
    - direct metal deposition (Direct Metal Deposition or DMD);
    - direct laser deposition (DLD);
    - Laser deposition technology;
    - laser engineering of net shapes (Laser Engineering Net Shaping);
    - laser cladding technology;
    - laser freeform manufacturing technology (LFMT);
    - laser fusion deposition (Laser Metal Deposition or LMD);
    - cold spraying (Cold Spray Consolidation or CSC);
    - additive friction manufacturing (Additive Friction Stir or AFS);
    - plasma spark sintering or flash sintering (Field Assisted Sintering Technology, FAST or spark plasma sintering); or
    - rotary friction welding (Inertia Rotary Friction Welding or IRFW).
    权利要求:
    Claims (1)
    [1" id="c-fr-0001]
    Claims [Claim 1] Method for manufacturing a part (20) comprising the formation of successive metal layers (20i ... 20 n ), superimposed on each other, each layer being formed by the deposition of a filler metal (15, 25 ), the filler metal being subjected to a supply of energy so as to melt and to constitute, by solidifying, said layer, the method being characterized in that the filler metal (15,25) is an aluminum alloy comprising the following alloying elements (% by weight): - Fe: 2% to 8%, and preferably 2% to 6%, more preferably 3 to 5%; - possibly Zr: 0.5% to 2.5% or 0.5 to 2% or 0.7 to 1.5%; - possibly Si: <1%, even <0.5% or even <0.2%, even <0.05%; - possibly Cu: <0.5%, even <0.2%, even <0.05%; - optionally Mg: <0.2%, preferably <0.1% preferably <0.05%; - possibly other alloying elements <0.1% individually and in total <0.5%; - impurities: <0.05%, even <0.01% individually, and in total <0.15%; remains aluminum. [Claim 2] Method according to claim 1, in which the other alloying elements are chosen from: Cr, V, Ti, Mn, Mo, W, Nb, Ta, Sc, Ni, Zn, Hf, Nd, Ce, Co, La, Ag, Li, Y, Yb, Er, Sn, In, Sb, Sr, Ba, Bi, Ca, P, B and / or mischmetal. [Claim 3] Method according to any one of the preceding claims, in which Zr: <0.5% or Zr <0.2% or Zr <0.05%. [Claim 4] Process according to any one of the preceding claims, in which the mass fraction of each other alloying element is less than 300 ppm, or even less than 200 ppm, or even less than 100 ppm. [Claim 5] Method according to any one of the preceding claims, in which:
    Fe: 2% to 8%;Zr: 0.5% to 2.5%;If: <0.5%. [Claim 6] Method according to any one of Claims 1 to 4, in which:Fe: 2% to 8%;Zr: <0.5%;If: <0.5%. [Claim 7] Method according to any one of the preceding claims, comprising, following the formation of the layers (20i ... 20 n ), an application of a heat treatment. [Claim 8] Process according to Claim 7, in which the heat treatment is annealing or annealing, carried out at a temperature preferably between 200 ° C and 500 ° C. [Claim 9] Method according to either of Claims 7 and 8, in which the heat treatment is carried out:- At a temperature between 200 ° C and less than 400 ° C, preferably from 320 to 380 ° C, in which case the duration of the heat treatment is between 0.1 and 20 hours;- Or at a temperature between 400 ° C and 500 ° C, in which case the duration of the heat treatment is between 0.1 and 5 hours. [Claim 10] Method according to any one of the preceding claims, not comprising quenching following the formation of the layers or the heat treatment. [Claim 11] Method according to any one of the preceding claims, in which the filler metal takes the form of a powder (15), the exposure of which to a beam of light (12) or of charged particles results in localized fusion followed solidification, so as to form a solid layer (20i ... 20 n ). [Claim 12] Process according to any one of Claims 1 to 10, in which the filler metal comes from a filler wire (25), the exposure of which to a heat source (22) results in localized melting followed solidification, so as to form a solid layer (20i ... 20 n ). [Claim 13] Piece obtained by a process which is the subject of any one of the resales
    previous indications.
    [Claim 14] Powder, intended to be used as filler material for an additive manufacturing process, characterized in that it consists of an aluminum alloy, comprising the following alloying elements (% in weight) :
    - Fe: 2% to 8%, and preferably 2% to 6%, more preferably 3 to 5%;
    - possibly Zr: 0.5% to 2.5% or 0.5 to 2% or 0.7 to 1.5%;
    - possibly Si: <1%, even <0.5% or even <0.2%, even <0.05%;
    - possibly Cu: <0.5%, even <0.2%, even <0.05%;
    - optionally Mg: <0.2%, preferably <0.1%, preferably <0.05%;
    - possibly other alloying elements <0.1% individually and in total <0.5%;
    - impurities: <0.05%, even <0.01% individually, and in total <0.15%;
    remains aluminum.
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    EP3860788A1|2021-08-11|
    FR3086873A1|2020-04-10|
    FR3086954B1|2021-12-10|
    CN112805107A|2021-05-14|
    WO2020070452A1|2020-04-09|
    CN112805105A|2021-05-14|
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    CN106055162B|2016-06-30|2019-05-03|京东方科技集团股份有限公司|Display component and display device|FR3110095A1|2020-05-13|2021-11-19|C-Tec Constellium Technology Center|Manufacturing process of an aluminum alloy part|
    CN113430422A|2021-06-25|2021-09-24|中南大学|High-strength high-toughness heat-resistant aluminum-iron alloy and 3D printing method thereof|
    法律状态:
    2020-07-27| PLFP| Fee payment|Year of fee payment: 2 |
    2020-10-09| PLSC| Publication of the preliminary search report|Effective date: 20201009 |
    2021-07-26| PLFP| Fee payment|Year of fee payment: 3 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1871133A|FR3086873A1|2018-10-05|2018-10-05|PROCESS FOR MANUFACTURING AN ALUMINUM ALLOY PART|
    FR1871133|2018-10-05|US17/282,262| US20210230716A1|2018-10-05|2019-10-03|Process for manufacturing an aluminium alloy part|
    CN201980065700.XA| CN112805107A|2018-10-05|2019-10-03|Method for manufacturing aluminum alloy parts|
    EP19801953.1A| EP3860789A1|2018-10-05|2019-10-03|Process for manufacturing an aluminium alloy part|
    PCT/FR2019/052348| WO2020070453A1|2018-10-05|2019-10-03|Process for manufacturing an aluminium alloy part|
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